The progress in synthesis of chiral phosphine ligands is reviewed. Their applications in asymmetric hydrogenation, asymm摘要本文较爲详细地综述了手性膦配体的合成进展,并介绍了其在不对称氢化反应、不对称氢甲酰化反应及不对称氢酯基化反应中的应用。
The hydroformylation of isoprene,1 octene,cyclopentadiene,and C 5 distillate where cyclopentadiene has been removed is s0MPa、180℃羰化反应条件下考察了异戊二烯、1-辛烯、环戊二烯、混合碳五馏份及脱去环戊二烯的碳五馏份的羰基合成反应。
This paper proposes a new technique for the recovery and regeneration of Rh catalyst for hydroformylation used in butano本文综述了国内外回收羰基合成Rh 催化剂的工艺方法和Rh 催化剂合成工艺,试验研究了大庆石化公司化工二厂的丁辛醇生产装置,乙酰丙酮三苯基膦羰基铑催化剂回收及Rh 催化剂合成工艺。
HYDROFORMYLATION OF SOME OLEFINS BY HETEROTETRANUCLEAR METAL CLUSTER [C_H_CH_Me_ N][RuCo_ (CO)_ ]钌钴簇合物[C_H_CH_Me_ N][RuCo_ (CO)_ ]对某些烯烃氢甲酰化反应的催化作用
Ln (TPPTS=tris ( m sulfonatophenyl) phosphine, Ln=Y, La ,Nd, Ho, Yb ) with RhCl , NiCl , PdCl were used as tL n(TPPTS=三 (间 -磺酸基苯基 )膦 ,L n=Y,L a,Nd,Ho,Yb)分别与 Rh Cl 、Ni Cl 、Pd Cl 组成的体系催化 -己烯氢甲酰化反应 .