The optimum technical conditions is as follow: ethanol as solvent, n[(C2H5)2NH]:n(CS2):n(H2O2,27.5%)=1.05:1.00:1.00, The reaction was carried out for 1 h at 20～30℃ to give tetraethyl thiuram disulfide in 88.0% yield.
The optimum technical conditions is as follow: ethanol as solvent, n[(C2H5)2NH]:n(CS2):n(H2O2,27.5%)=1.05:1.00:1.00, The reaction was carried out for 1 h at 20～30℃ to give tetraethyl thiuram disulfide in 88.0% yield.
得出最佳工艺条件为：无水乙醇为溶剂，二乙胺：二硫化碳：双氧水=1.05:1.00:1.00，反应时间1h，反应温度20～30℃，收率达到88.0%。