A possible mechanism involving samariun(Ⅲ) enolate intermediate formed in situ from α-haloketone with both Sm (Ⅱ) and Sm (Ⅲ)/Ⅰ~- species was proposed.
A possible mechanism involving samariun(Ⅲ) enolate intermediate formed in situ from α-haloketone with both Sm (Ⅱ) and Sm (Ⅲ)/Ⅰ~- species was proposed.
同时提出了涉及由α-卤代酮同时与Sm(Ⅱ)和Sm(Ⅲ)/Ⅰ~-物种作用形成烯醇钐盐中间体的可能机理。