Highly optically pure sex pheromone of gypsy moth porthetria dispar (7R, 8S)-a was synthesized via asymmetric sharpless epoxidation of a divinylcarbinol (>99% e.e.) and the subsequent chemical transformations in an overall yield of .9%.
Highly optically pure sex pheromone of gypsy moth porthetria dispar (7R, 8S)-a was synthesized via asymmetric sharpless epoxidation of a divinylcarbinol (>99% e.e.) and the subsequent chemical transformations in an overall yield of .9%.
双乙烯基甲醇经过Sharpless不对称环氧化反应合成到高光学纯的午毒蛾Porthetria dispar性信息素(7R,8S)-a,对映体过量大于99％,总产率达 .9％。