The reaction of C 0 with azide is by nitrene mechanism. In order to control the reaction and obtain the monoaddition product, the part of the spherical of C 0 was blocked by adding γ-cyclodextrin into the mixture of the reaction.
The reaction of C 0 with azide is by nitrene mechanism. In order to control the reaction and obtain the monoaddition product, the part of the spherical of C 0 was blocked by adding γ-cyclodextrin into the mixture of the reaction.
碳－0经氮烯机理与叠氮化物发生反应，为了控制其反应并得到单加成产物，通过加入γ－环糊精使碳－0球面部分封闭起来，从而得到了理想的单加成产物。